Poly[aqua[μ-4-(4-chlorophenyl)-2-thioxo-2,3-dihydrothiazol-3-olato]sodium(I)]
نویسندگان
چکیده
The packing of the title compound, [Na(C(9)H(5)ClNOS(2))(H(2)O)](n), in the crystal structure occurs by pairwise attachment of +sc- and -sc-arranged 4-(4-chloro-phen-yl)-2-thioxo-2,3-dihydro-thia-zol-3-olate subunits via S to sodium. Water mol-ecules that are bound in the axial position of the distorted octa-hedral coordination octahedron give rise to a stereogenic center at sodium.
منابع مشابه
Poly[aqua(μ1,1-azido)(μ-3H-1,2,3-triazolo[4,5-b]pyridin-3-olato)cobalt(II)]
In the title compound, [Co(C(5)H(3)N(4)O)(N(3))(H(2)O)](n), the cobalt ion is coordinated by three N atoms of two organic ligands, two N atoms of two azide anions and one water mol-ecule in a distorted octa-hedral geometry. The metal atoms are connected via the ligands into layers, which are further connected by O-H⋯N and O-H⋯O hydrogen bonding.
متن کاملSynthesis, anti-inflammatory and analgesic evaluation of thioxoquinazolinone derivatives.
A series of 3-substituted-2-thioxoquinazolin-4(3H)-one derivatives have been synthesized and their structures have been elucidated on the basis of IR, (1)H-NMR, elemental analysis and mass spectroscopic studies. Anti-inflammatory and analgesic activity of the synthesized compounds was evaluated by Carrageenan induced rat paw edema method and Eddy's hot plate method respectively. Among the synth...
متن کاملcatena-Poly[[[aqua(pyridine-4-carboxylato-κN)silver(I)]-μ-hexamethylenetetraamine-κ2 N:N′] dihydrate]
In the title compound, {[Ag(C(6)H(4)NO(2))(C(6)H(12)N(4))(H(2)O)]·2H(2)O}(n), the Ag(I) atom shows a distorted triangular pyramidal geometry,, formed by two N atoms from two hexa-methyl-ene-tetra-amine (hmt) ligands and one N atom from a pyridine-4-carboxyl-ate (4-pdc) ligand and one water mol-ecule. The hmt ligands bridge the Ag atoms, forming a chain along [001]. The carboxyl-ate group of the...
متن کاملcatena-Poly[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ2 N 8,N 9)cobalt(II)]-μ-pyrazine-2,3-dicarboxylato-κ3 N 1 O 2:O 3]
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متن کاملcatena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ2 N 4,N 5)iron(II)]-μ-pyrazine-2,3-dicarboxylato-κ3 N 1,O 2:O 3]
In the title compound, [Fe(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n), the Fe(II) ion adopts a slightly distorted octahedral mer-FeN(3)O(3) geometry, arising from one N,N'-bidentate dipyrido[3,2-a:2',3'-c]phenazine ligand, one N,O-chelating pyrazine-2,3-dicarboxyl-ate dianion and one water mol-ecule. An O-bonded symmetry-related dianion completes the coordination of the metal. The bridging di...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008